Search results for "chiroptical inversion"

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Chiroptical inversion of a planar chiral redox-switchable rotaxane.

2019

Reversible redox-switching of a planar chiral [2]rotaxane with a tetrathiafulvalene-bearing crown ether macrocycle generates a complete sign reversal of the main band in the ECD spectrum, as shown by experiment and rationalised by DFT calculations.

chemistry.chemical_classificationMaterials scienceRotaxane010405 organic chemistryGeneral Chemistry547Planar chirality010402 general chemistryElectrochemistry01 natural sciences0104 chemical sciencesChiral column chromatographyCrystallographychemistry.chemical_compoundChemistry500 Naturwissenschaften und Mathematik::540 Chemie::547 Organische Chemieredox-switchablechemistryElectronic effectrotaxanechiroptical inversionEnantiomermakromolekyylitTetrathiafulvaleneCrown etherChemical science

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